acyclic diene metathesis



Die acyclische Dienmetathese-Polymerisation (englisch acyclic diene metathesis), auch ADMET-Polymerisation genannt, ist eine Variante der Alkenmetathese, bei der Diolefine mit endständigen Doppelbindungen (α,ω-Diene) in einer als Stufenwachstumsreaktion ablaufenden Gleichgewichtsreaktion in Gegenwart von
Abstract. The history of and major advances in the acyclic diene metathesis (ADMET) reaction are described. Because precise branch identity and frequency can be achieved by ADMET polymerizations of symmetrical α,ω-dienes, polyethylenes with precisely spaced alkyl branches of specified length have been prepared.
23.09.2009 -
Acyclic Diene Metathesis (ADMET) polymerization was established decades ago and has since developed into a robust and reliable technique. A wide range of different, new materials exhibiting unique properties has been produced via ADMET polymerization since its development. This versatile technique allows, through
4 Acyclic Diene Metathesis (ADMET) Polymerization. Tammy A. Davidson and Kenneth B. Wagener. The George and Josephine Butler Polymer Research Laboratory, Department of Chemistry and Center for Macromolecular Science and Engineering, University of Florida, Gaines- ville, FL, U.S.A.. List of Symbols and
19.07.2016 -
Ph)(PCy3)2, [Ru] 3, metathesis catalyst under acyclic diene metathesis (ADMET) conditions, and the products were compared with those obtained previously using Schrock's well defined Mo and W alkylidenes. High molecular weight polymers can be synthesized using [Ru] 3 if lower monomer to catalyst ratios with respect
01.05.1991 -
Acyclic Diene Metathesis (ADMET) Polymerization. Design and. Synthesis of Unsaturated Poly(carbosi1oxane)s. D. W. Smith, Jr., and K. B. Wagener'. Department of Chemistry and Center for Macromolecular Science and Engineering,. University of Florida, Gainesuille, Florida 3261 1-2046. Received July 27, 1992; Revised

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